The City of Alliance is located in Stark County, with a small area located in Mahoning County. The city is approximately 18 miles northeast of Canton, approximately 55 miles southeast of Cleveland, and approximately 79 miles northwest of Pittsburgh, Pennsylvania.
Nearest Interstate Highways are 76, 77, and 80. Amtrak, which provides freight and passenger rail services through a station located in the city as well. Akron-Canton Regional Airport located 25 miles west of the city, the Youngstown/Warren Regional Municipal Airport located 35 miles northeast of the city, and Cleveland Hopkins International Airport located 55 miles northwest of the city.